Testing For Cations And Anions Lab Answers


  • Explain the scientific principles behind the tests used to identify chemicals? Please see the newly added section "What is Cation Testing" in this article. Is there any easy way in memorizing the tests for cations and anions? I find it quite...
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  • Thank you so much. It says that obtain a few crystals of table salt on the tip of a clean scoopula and place the tip in the flame of a bunsen burner under the hood. Elements have characteristic colors when placed in a flame. Test strontium nitrate,...
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  • Is there a trend with adding NaOH to Period 3 elements? In the paper, I was asked to identify one simple test-tube reaction to distinguish between aqueous solutions of magnesium chloride, MgCl2, and aluminium chloride, AlCl3. As I have never really come across this before, I was wondering if you could explain the trend with adding NaOH to Period 3 chlorides and other metal ions please, such as if they produce different coloured precipitates or if they react differently and why. For example, why does the AlCl3 precipitate dissolve with excess? I would very much like to know the role of the OH-. Thank you very much in advance. It involves the testing of metal ions not shown in the tables and further explanation. I have tried: My Chemistry A-level textbook and other websites, I feel this is a great place to find the answer.
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  • I think it was caused by: Having to apply reactions to other scenarios and apply trends to different groups ScienceAid QnA. Referencing this Article If you need to reference this article in your work, you can copy-paste the following depending on your required format: APA American Psychological Association Testing for Cations.
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  • In ScienceAid. If you have problems with any of the steps in this article, please ask a question for more help, or post in the comments section below.
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  • Our objective is to determine the anion present in the given salt. The qualitative inorganic analysis is a method of analytical chemistry that seeks to find out the elemental composition of inorganic compounds through various reagents. It is mainly focused on detection of ions in an aqueous solution, so the substances in other states need to be converted into an aqueous solution before starting the experiment.
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  • The procedure for detecting ions cations and anions in aqueous solutions are called Cation Analysis and Anion Analysis. Let's discuss the Qualitative Analysis of Anions. Qualitative Analysis of Anions Some preliminary tests are done before going to the anion analysis. A Physical Examination: Colour and Smell The physical examination of the unknown salt involves the study of colour, smell and density. Characteristic smell helps to identify some anions such as acetate, sulphide etc. B Dry Heating Test This test is performed by heating a small amount of salt in a dry test tube. Quite valuable information can be gathered by carefully performing and noting the observations. On heating, some salts undergo decomposition, thus evolving the gases. C Identification of Anions Acid Radicals The identification of the radicals is first done on the basis of the preliminary tests. The Dry heating test is one of the preliminary tests performed earlier which may give some important information about the acid radical present.
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  • These gases on identification indicate the nature of the anion present in the salt. H2SO4 but not with dil. H2SO4 to produce characteristic gases. These are, therefore, identified by individual tests. Thus, these anions may be identified by performing the following tests below: 1 Dil. H2SO4 Tests Treat a pinch of the salt with dil. H2SO4 and identify the gas evolved. Chemical Reactions Involved in Dil. H2SO4 give H2S gas. H2SO4 Test If no action takes place with dil. H2SO4, warm a pinch of the salt with conc. Chemical Reactions Involved in Conc. H2SO4 to evolve hydrogen chloride HCl gas. H2SO4 to evolve bromine gas. H2SO4 to evolve vapours of iodine. H2SO4 nitrates evolve NO2 gas. H2SO4 to produce vapours of acetic acid.
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  • H2SO4 to evolve a mixture of carbon dioxide and carbon monoxide. HCl gives CO2 gas that reacts with lime water to produce a white precipitate of calcium carbonate that turns lime water milky. In case of soluble carbonate, this test is performed with water extract and in case of insoluble carbonates, this test is performed with the solid salt. Soluble carbonates react with the magnesium sulphate solution to form a white precipitate of magnesium carbonate. Confirmation of Sulphite SO a Barium chloride test Sulphites on reaction with barium chloride to form a white precipitate of barium sulphite.
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  • Barium sulphite dissolved in dil. HCl with the evolution of sulphur dioxide gas. The reaction is given below. Iodine forms a blue-black complex with starch. Confirmation of Nitrate NO3- In the presence of nitrates, diphenylamine is oxidised, giving a blue colouration. The formation of a brown ring at the junction of two layers indicates the presence of nitrate. Confirmation of Chloride Cl- a Silver nitrate test Chlorides on reaction with silver nitrate solution to form a white precipitate of silver chloride which is soluble in ammonium hydroxide. Sodium chromate reacts with lead acetate in presence of dil. Confirmation of Bromide Br- a Silver nitrate test Bromides on reaction with silver nitrate solution forms a pale yellow precipitate of silver bromide which is sparingly soluble in ammonium hydroxide. Note: Carbon tetrachloride, cyclohexane, chloroform etc can be used instead of carbon disulphide.
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  • Confirmation of Iodide I- a Silver nitrate test Iodides on reaction with silver nitrate solution forms an yellow precipitate of silver iodide which is insoluble in ammonium hydroxide. Confirmation of Acetate CH3COO- a Oxalic acid test Oxalic acid reacts with acetate salt to form acetic acid which has a characteristic vinegar like smell. Confirmation of Oxalate C2O Oxalate salts react with calcium chloride to form white precipitate of calcium oxalate.
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  • Confirmation of Sulphate SO Sulphates react with barium chloride to form white precipitate of barium sulphate. Confirmation of Phosphate PO a Ammonium molybdate test Phosphate salts react with ammonium molybdate solution to form a deep yellow precipitate of ammonium phosphate molybdate. The chemical reaction is as follows: b Magnesia mixture test Phosphate salts react with magnesia mixture to form white precipitate of magnesium ammonium phosphate. Note: To prepare magnesia mixture, add solid NH4Cl to magnesium chloride solution. Boil, cool and add NH4OH till a strong smell of ammonia ia obtained. Learning Outcomes: Students understand different types of anions. Students understand various tests to identify the anion present in a given salt. Students understand the chemical reactions and their balanced equations that takes place during each test. Students acquire the skill to perform the experiment in the real lab once they understand different steps in the procedure.
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  • Experiment Date : October 18th, at End of The Experiment : October 18th, at Experiment Purpose : 1. To determine the cation which can be found in the analite 2. To determine the anion which can be found in the analite V. Basic Theory A. Qualitative Analysis Chemical analysis can be divided into two categories; qualitative analysis what is present and quantitative analysis how much is present. Qualitative ana- lysis involves the detection of elements that are found in an organic compound. Qualitative analysis can only detect the presence of elements in the compound but cannot determine the percentage or amount of them in the compound. For example; carbon and hydrogen are detected with the help of Liebig s method. Some other common elements which can be determined are oxygen, halogen, sulphur, nitrogen, halogens, sulphur and phosphorus.
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  • Qualitative analysis is a type of chemical analysis which is used to separate and detect cation and anions in a sample substance. The chemical properties of an unknown substance are determined in the qualitative analysis procedure by the reaction between the unknown substance and suitable reagents. The qualitative analysis is used for the identification of a simple salt or the identification of various cations present in a solution. Cations Cations are divided into five groups. A specific reagent for each group is used for their separation from the solution. This separation is done in a particular se- quence because some ions of prior groups can also react with the reagent of later groups. Experiment Report: Analysis of Anions and Cations 1 This can be cause of difficulty in their separation. The qualitative analysis of cations depends on the solubility products of the ions. The cations get precipitated on the optimum needed concentration and easily detected.
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  • The other groups will remain in solution thus allowing the Group I chloride precipitates to be removed and further tested. Colour detection test is not suitable for their chlorides because all are white solid compounds. The analysing of group is done by adding the respective salt into water and follow it with dilute HCl. This results in a white precipitate in which NH4OH is added. The tests are conducted in presence of dilute HCl to keep the S 2- ion concen- tration at a minimum level. This round of tests helps only in second 2nd gro- up cations precipitation. The cations precipitation of the 4th group if present in the solution might occur in the absence of dilute HCl which can give wrong results. The use of sulphuric acid and nitric acid can cause to the precipitation of the 4th group cations and formation of colloidal sulphur respectively. This group is determined by the addition of the respective salt in water and then adding dilute HCl and then follow it by adding H 2S.
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  • However they form precipitates with ammonium sulphides NH4 2S in neutral or ammonical medium. They precipitate with ammonium carbonate NH 4 CO3 in the pre- sence of ammonium chloride in neutral medium. The result of experiment and the presence of the respective ions are shown in the table below. It can be identified by special reaction or by flame test. Magnesium cation showing similar reaction with group IV cations. Sodium and potassium ion are from group IA Alkaline , and they have similarity.
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  • Both of them are big enough, colourless, can not reduced in solution state, so it can not react with water. Anions The methods available for the detection of anions are not as systematic as those which have been described above for cations. No really satisfactory scheme has yet been proposed which permits the separation of the common anions into major groups, and the subsequent unequivocal separation of each group into its independent constituents; however, it is possible to detect anions individually in most cases, after perhaps a stage separation. It is advantageous to remove all heavy metals from the sample by extracting the anions through boiling with sodium carbonate solution; heavy metal ions are precipitated out in the form of carbonates, while the anions remain in solution accompanied by sodium ions. The following scheme of classification of anions has been found to work well in practice; anions are divided into four groups on the basis of their reactions with di- lute hydrochloric acid and of the differences of solubilities of their barium and sil- ver salts.
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  • However, they form precipitates with silver ions in dilute nitric acid medium. To identify nitrate ion can be done by brown ring test which can be done by adding concentrate H2S04 and then adding saturated FeSO4 little by little through the tube wall. Tools and Material A. Tools B. Materials 1. Test tube 1. Sample NH4NO3 2. Pipettes 2. NaOH solution 3. Litmus paper 3. Saturated Na2CO3 4. Test tube rack 4. Concentrated H2SO4 5. Filter paper 5. Saturated FeSO4 6. Tripod 7. Funnel 8. Beaker glass 9. Bunsen burner VII.
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  • Flow Chart A. Analysis In this experiment we got sample number two which has form colourless crystal through random selection. First of all we are dividing the sample into three with ratio First, we are entering some of the sample into reaction tube. Then, we adding 6 drops of NaOH to the tube, the sample turn its form from colourless crystals to colourless solution.
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  • After that, we are put the red litmus paper above the tube and enter the half part of the litmus into the tube. After a while the red lit- mus paper changes its colour from red to blue. Preparation of Anion Test In this experiment we analysing the contents of anion in the sample number two. First we adding saturated Na2CO3 into the sample, the sample turn its form from colourless crystal to colour solution. Then, we heating the solution with steam bath water for about 10 minutes until white sediment formed. Next, the heating result is filtered. We obtain colour- less solution as the filtrate which will be used for anion test. Then, we are dividing the filt- rate into 3 for testing anion contents. First, we adding 2 drops of concentrate H2SO4 into the test tube which contains filtrate from prepa- ration solution.
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